Please use this identifier to cite or link to this item: https://hdl.handle.net/20.500.12104/42892
Title: Models for oscillating polymerization: Activation by product in a system with flow
Author: Katime, I.
Perez Ortiz, J.A.
Morales, J.A.
Mendizábal, E. M.
Issue Date: 2014
Abstract: In this work, four polymerization mechanisms with flow are proposed where sustained oscillation can be present: (1) Polyaddition initiated by radicals produced by initiator decomposition, which is catalyzed by the polymer, first-order termination, a polymer disappears by a reaction with a third substance and by leaving the system in the exit flow. (2) Polycondensation where the polymer has catalytic activity upon H to produce a monomer, first-order termination and a monomer disappears by a reaction with a third substance, and there is exit flow for all the species. (3) Polycondensation with catalytic activity of the polymer upon A to produce a monomer, first-order termination, conformational transitions of the polymers, one of the polymer conformations disappears by a reaction with a monomer and exit flow for all the species. (4) Polycondensation combined with polyaddition where the polycondensation polymer product has catalytic activity on the monomer, first-order termination and exit flow of all the species. © 2014 Wiley Periodicals, Inc.
URI: http://www.scopus.com/inward/record.url?eid=2-s2.0-84899548945&partnerID=40&md5=3540ded1622465577fe6e0b60c2bf0e7
http://hdl.handle.net/20.500.12104/42892
Appears in Collections:Producción científica UdeG

Files in This Item:
There are no files associated with this item.


Items in RIUdeG are protected by copyright, with all rights reserved, unless otherwise indicated.