Please use this identifier to cite or link to this item: https://hdl.handle.net/20.500.12104/42862
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dc.contributor.authorKatime, I.-
dc.contributor.authorPerez Ortiz, J.A.-
dc.contributor.authorZuluaga, F.-
dc.contributor.authorMendizábal, E. M.-
dc.date.accessioned2015-09-15T18:24:39Z-
dc.date.available2015-09-15T18:24:39Z-
dc.date.issued2010-
dc.identifier.urihttp://www.scopus.com/inward/record.url?eid=2-s2.0-77957915575&partnerID=40&md5=1d8e0eaf9dbe32e0b631ed777fb481b1-
dc.identifier.urihttp://hdl.handle.net/20.500.12104/42862-
dc.description.abstractA simple polymerization scheme. {X?R1 Rj+X?Rj+1 (j=1,2,...,?) Ri+Rj?polymer (i=1,2,...?j=1,2,...,?) has been studied introducing small modifications leading to a stable focus type steady state (with damped oscillations) or unstable focus type (which combined with a no return enclosure for phase trajectories will show cycle limit sustained oscillations). Two variables have been employed in this analysis: X? monomer, Y??j=1 ?Rj = radicals. Limit cycle oscillations requires the addition of autocatalysis with respect to the monomer, J+. X?2. X, and so does an "enzymatic" block. {U+X?VV?Uassuming that Ü=0. The combination of both collateral additions makes the steady state an unstable focus and allows a simple Poincaré-Bendixson proof for the existence of the limit cycle. © 2010 Elsevier Ltd.-
dc.relation.isreferencedbyScopus-
dc.relation.isreferencedbyWOS-
dc.titleMinimum models of damped and limit cycle oscillations in a polymerization-
dc.typeArticle-
dc.identifier.doi10.1016/j.ces.2010.09.015-
dc.relation.ispartofjournalChemical Engineering Science-
dc.relation.ispartofvolume65-
dc.relation.ispartofissue23-
dc.relation.ispartofpage6292-
dc.relation.ispartofpage6295-
dc.subject.keywordIsothermal; Kinetics; Limit cycle; Nonlinear dynamics; Polymerization; Polymers-
dc.contributor.affiliationKatime, I., Grupo de Nuevos Materiales y Espectroscopia Supramolecular, Facultad de Ciencia y Tecnología, Universidad del País Vasco (UPV/EHU), Campus de Lejona, Bilbao, Spain; Pérez Ortiz, J.A., Grupo de Nuevos Materiales y Espectroscopia Supramolecular, Facultad de Ciencia y Tecnología, Universidad del País Vasco (UPV/EHU), Campus de Lejona, Bilbao, Spain; Zuluaga, F., Departamento de Química, Universidad del Valle, Colombia; Mendizábal, E., Universidad de Guadalajara, Departamento de Química, Guadalajara, Jalisco, Mexico-
dc.contributor.affiliationMendizábal, E. M., Universidad de Guadalajara. Centro Universitario de Ciencias Exactas e Ingenierías-
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