Please use this identifier to cite or link to this item: https://hdl.handle.net/20.500.12104/40606
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dc.contributor.authorGonzalez-Ortiz, L.J.
dc.contributor.authorAsua, J.M.
dc.date.accessioned2015-09-15T17:41:12Z-
dc.date.available2015-09-15T17:41:12Z-
dc.date.issued1996
dc.identifier.urihttp://hdl.handle.net/20.500.12104/40606-
dc.identifier.urihttp://www.scopus.com/inward/record.url?eid=2-s2.0-0342687427&partnerID=40&md5=496039208eea197269fc949aef78fb0f
dc.identifier.urihttp://dx.doi.org/10.1021/ma950512b
dc.description.abstractA mathematical model for the development of particle morphology in emulsion polymerization has been developed. The polymer particles are considered to be a biphasic system comprising clusters of polymer 1 dispersed in a matrix of polymer 2. The model accounts for both polymerization and cluster migration. Polymerization of monomer 1 occurs both in the polymer matrix and in the clusters. The polymer 1 formed in the matrix diffuses instantaneously into the clusters. The clusters migrate toward the equilibrium morphology to minimize the free energy of the system. The driving forces for the motion of the clusters are the van der Waals interaction forces between the clusters and the aqueous phase and those between the clusters themselves. The effect of polymer matrix viscosity on the cluster motion is included. Illustrative simulations and comparisons with experimental data are presented.
dc.relation.isreferencedbyScopus
dc.relation.isreferencedbyChemAbsS
dc.titleDevelopment of particle morphology in emulsion polymerization. 2. Cluster dynamics in reacting systems
dc.typeArticle
dc.relation.ispartofjournalMacromolecules
dc.relation.ispartofvolume29
dc.relation.ispartofissue1
dc.relation.ispartofpage383
dc.relation.ispartofpage389
dc.contributor.affiliationGonzález-Ortiz, L.J., Depto. de Química Aplicada, Facultad de Ciencias Químicas, Universidad del País Vasco, Apartado 1072, 20080 San Sebastián, Spain, Universidad de Guadalajara, Guadalajara, Mexico; Asua, J.M., Depto. de Química Aplicada, Facultad de Ciencias Químicas, Universidad del País Vasco, Apartado 1072, 20080 San Sebastián, Spain
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